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A δ2H Isoscape of blackberry as an example application for determining the geographic origins of plant materials in New Zealand


Autoři: Kiri McComb aff001;  Shaerii Sarker aff002;  Jurian Hoogewerff aff003;  Alan Hayman aff001;  Russell Frew aff001
Působiště autorů: Department of Chemistry, University of Otago, Dunedin, New Zealand aff001;  Global Proficiency Limited, Hamilton, New Zealand aff002;  Faculty of Science & Technology, University of Canberra, Canberra, Australia aff003
Vyšlo v časopise: PLoS ONE 14(12)
Kategorie: Research Article
doi: https://doi.org/10.1371/journal.pone.0226152

Souhrn

In this investigation, two previously reported precipitation δ2H isoscapes for New Zealand were used to develop a δ2H isoscape for blackberry (Rubus sp.) leaf. These isoscapes were calibrated using the measured δ2H values of 120 authentic blackberry leaf samples collected from across the country. A regression model based on environmental variables available for New Zealand was also determined to predict δ2H values measured from blackberry leaves without initially modelling the precipitation δ2H values. The three models were compared for their accuracy and precision when assigning 10 samples of blackberry leaves for their geographic location based on their measured δ2H values. One of the models based on a precipitation isoscape was similar in accuracy and precision of assignment to the model determined from the environmental variables and provides an approach for determining valid isoscapes for future plant materials.

Klíčová slova:

Environmental geography – Islands – Leaves – Meteorology – New Zealand – Rain – Natural materials


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